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Miniaturized photoionization detectors (PIDs) are used in conjunction with gas chromatography systems to detect volatile compounds in gases by collecting the current from the photoionized gas analytes. PIDs should be inexpensive and compatible with a wide range of analyte species. One such PID is based on the formation of a He plasma in a dielectric barrier discharge (DBD), which generates vacuum UV (VUV) photons from excited states of He to photoionize gas analytes. There are several design parameters that can be leveraged to increase the ionizing photon flux to gas analytes to increase the sensitivity of the PID. To that end, the methods to maximize the photon flux from a pulsed He plasma in a DBD-PID were investigated using a two-dimensional plasma hydrodynamics model. The ionizing photon flux originated from the resonance states of helium, He(3P) and He(21P), and from the dimer excimer He2*. While the photon flux from the resonant states was modulated over the voltage pulse, the photon flux from He2* persisted long after the voltage pulse passed. Several geometrical optimizations were investigated, such as using an array of pointed electrodes. However, increasing the capacitance of the dielectric enclosing the plasma chamber had the largest effect on increasing the VUV photon fluence to gas analytes. 

Abstract The water supply network (WSN) is subjected to leaks that compromise its service to the communities, which, however, is challenging to identify with conventional approaches before the consequences surface. This study developed Machine Learning (ML) models to detect leaks in the WDN. Water pressure data under leaking versus non-leaking conditions were generated with holistic WSN simulation code EPANET considering factors such as the fluctuating user demands, data noise, and the extent of leaks, etc. The results indicate that Artificial Neural Network (ANN), a supervised ML model, can accurately classify leaking versus non-leaking conditions; it, however, requires balanced dataset under both leaking and non-leaking conditions, which is difficult for a real WSN that mostly operate under normal service condition. Autoencoder neural network (AE), an unsupervised ML model, is further developed to detect leak with unbalanced data. The results show AE ML model achieved high accuracy when leaks occur in pipes inside the sensor monitoring area, while the accuracy is compromised otherwise. This observation will provide guidelines to deploy monitoring sensors to cover the desired monitoring area. A novel strategy is proposed based on multiple independent detection attempts to further increase the reliability of leak detection by the AE and is found to significantly reduce the probability of false alarm. The trained AE model and leak detection strategy is further tested on a testbed WSN and achieved promising results. The ML model and leak detection strategy can be readily deployed for in-service WSNs using data obtained with internet-of-things (IoTs) technologies such as smart meters.